Hive should be used for analytical querying of data collected over a period of time - for instance, to calculate trends or website logs. Hive should not be used for real-time querying since it could take a while before any results are returned.
HBase is perfect for real-time querying of Big Data.HBase should be used when –
MapReduce is a computing framework. HBase nothing to do with it. That said, you can efficiently fetch data from HBase by writing MapReduce jobs. Alternatively you can write sequential programs using other HBase APIs, such as Java, to put or fetch the data. But we use Hadoop, HBase etc to deal with gigantic amounts of data, so that doesn't make much sense. Using normal sequential programs would be highly inefficient when your data is too huge.
Coming back to the first part of your question, Hadoop is basically 2 things: a Distributed FileSystem (HDFS) + a Computation or Processing framework (MapReduce). Like all other FS, HDFS also provides us storage, but in a fault tolerant manner with high throughput and lower risk of data loss (because of the replication). But, being a FS, HDFS lacks random read and write access. This is where HBase comes into picture. It's a distributed, scalable, big data store, modelled after Google's BigTable. It stores data as key/value pairs.
Coming to Hive. It provides us data warehousing facilities on top of an existing Hadoop cluster. Along with that it provides an SQL like interface which makes your work easier, in case you are coming from an SQL background. You can create tables in Hive and store data there. Along with that you can even map your existing HBase tables to Hive and operate on them.
While Pig is basically a dataflow language that allows us to process enormous amounts of data very easily and quickly. Pig basically has 2 parts: the Pig Interpreter and the language, PigLatin. You write Pig script in PigLatin and using Pig interpreter process them. Pig makes our life a lot easier, otherwise writing MapReduce is always not easy. In fact in some cases it can really become a pain.